Genesis of clay minerals and about the genesis and postsedimentation changes of clayey minerals of Mezo-Cenozoic deposits in Azerbaijan
Kheirov M.B.
Processes of lithogenesis play an important
role in the formation of geological peculiarities of oil and gas deposits.
Processes of lithogenesis of clays
and clayey minerals start since the moment of entry into the sedimentation
basin. This is due to the ion-exchange reactions between the clayey minerals
and ions of the sea water, and a special role is played by ions Mg2+
and K+. They promote the formation of dior trioctahedral clayey
minerals in the basin.
In the process of lithofication of
sediments, depending on physical-chemical peculiarities and geochemical
environment in the basin, there occurs the formation of various minerals by the
authigenic way.
In the reduction geochemical medium
there takes place the formation of the authigenic montmorillonite of the volcanic
material.
In lagoons with high salinity of
waters, there have been formed magnesian minerals of a chain-like structure (paligorskite,
sepiolite).
During the subsidence of the
sediments to large depth, there occur perceived katagenetic changes under the
influence of increased values of thermobaric parameters. Rate of these
processes in the lithofacial clays in not high due to a not intensive migration
of ions. The swelling clayey minerals there may be preserved at depth more than
6–7 km. At rather high temperatures, the water may be removed out of them
irreversably. But this does not mean the conversation of montmorillonite into chlorite
or sericite. For this process the existence of elements necessary for the
formation of chlorite or micas as well as conditions for their migration in a
rock are required.